This innovative spiderweb-inspired composite offers a unique combination of transparency and impact absorption. Its rapid fabrication is made possible through instability-assisted 3D printing, which enables precise and efficient production. The composite exhibits high damage tolerance and hysteresis, making it highly effective in stopping projectiles. With its exceptional properties, this material holds great potential for use in structural applications, bullet-proof or spacecraft windows, and sports protective equipment. Its design and capabilities are poised to revolutionize safety and performance in various fields.